全文获取类型
收费全文 | 7582篇 |
免费 | 1012篇 |
国内免费 | 895篇 |
专业分类
化学 | 2170篇 |
晶体学 | 44篇 |
力学 | 595篇 |
综合类 | 120篇 |
数学 | 4227篇 |
物理学 | 2333篇 |
出版年
2024年 | 8篇 |
2023年 | 85篇 |
2022年 | 128篇 |
2021年 | 189篇 |
2020年 | 258篇 |
2019年 | 216篇 |
2018年 | 228篇 |
2017年 | 252篇 |
2016年 | 290篇 |
2015年 | 207篇 |
2014年 | 311篇 |
2013年 | 729篇 |
2012年 | 390篇 |
2011年 | 449篇 |
2010年 | 404篇 |
2009年 | 511篇 |
2008年 | 511篇 |
2007年 | 550篇 |
2006年 | 461篇 |
2005年 | 396篇 |
2004年 | 342篇 |
2003年 | 376篇 |
2002年 | 347篇 |
2001年 | 274篇 |
2000年 | 210篇 |
1999年 | 188篇 |
1998年 | 217篇 |
1997年 | 177篇 |
1996年 | 132篇 |
1995年 | 93篇 |
1994年 | 76篇 |
1993年 | 63篇 |
1992年 | 51篇 |
1991年 | 51篇 |
1990年 | 34篇 |
1989年 | 31篇 |
1988年 | 35篇 |
1987年 | 31篇 |
1986年 | 20篇 |
1985年 | 36篇 |
1984年 | 24篇 |
1983年 | 11篇 |
1982年 | 25篇 |
1981年 | 10篇 |
1980年 | 10篇 |
1979年 | 9篇 |
1978年 | 9篇 |
1977年 | 8篇 |
1976年 | 9篇 |
1973年 | 6篇 |
排序方式: 共有9489条查询结果,搜索用时 312 毫秒
61.
研究了非奇H-矩阵的判定问题.先给出了几个判定严格α-双链对角占优矩阵的充要条件,进一步利用矩阵对角占优理论得到了判定非奇H-矩阵的一些充分条件,推广和改进了已有的相关结果,并用数值算例说明了这些判定方法的有效性. 相似文献
62.
从矩阵几何解的角度出发,分析了七种类型的Geom/Geom/(Geom/Geom)/H 双输入排队系统.对这几个模型进行了描述,使用拟生灭过程探讨了各类模型的矩阵结构,并给出了其状态转移概率矩阵. 相似文献
63.
对于聚集数据的线性模型,提出了广义聚集双参数估计的概念,给出了广义聚集双参数估计的两种相对效率,并得到了这两种相对效率的上界. 相似文献
64.
对于呈现自相关和波动族聚性并存的受控过程,通常采用残差控制图对其进行监控。但异常点的存在会对自相关或波动族聚性模型的拟合产生重要影响,使得基于该模型的残差并非独立同分布导致常规残差控制图监控失效。为解决这类问题,本文提出稳健残差控制图。即建立稳健的ARMA模型解决自相关问题从而得到无自相关的残差序列,用稳健的GARCH模型来构建控制图的上下限。模拟和实证研究表明,本文提出的稳健残差控制图具有很好的抗异常点能力并能更好的对金融时间序列的异常现象进行监控。 相似文献
65.
Uncatalyzed peptide bond formation between two double amino acid molecules in the gas phase 下载免费PDF全文
The gas phase mechanism for peptide bond formation between two double amino acid (DAA) molecules ((NH2)2C(COOH)2) is investigated in the absence of any catalysts. Two different paths, concerted and stepwise, each leading to both cis and trans DAA‐DAA dipeptide products (four mechanisms total) are examined on the basis of theoretical calculations carried out at the CCSD(T)/aug‐cc‐pVDZ//MP2/aug‐cc‐pVDZ level. The investigation indicates that the concerted mechanism leading to the trans configuration of the peptide bond in the DAA‐DAA dipeptide product is thermodynamically favored by about 5 kcal mol?1 and requires slightly less energy than the remaining pathways considered. Moreover, the peptide bond formation process between two DAA molecules in the gas phase resembles the analogous reactions between two natural amino acids. 相似文献
66.
Aniruddha Das 《合成通讯》2017,47(23):2254-2267
Investigation into Sonogashira reaction on 5-iodo-1-(phenyl/p-halophenyl)imidazole-4-carbonitrile compounds had been developed by introducing an iodo atom at the C-5 position of the imidazole ring of 5-amino-1-(phenyl/p-halophenyl)imidazole-4-carbonitrile compounds. Specifically, 5-iodo-1-(4-iodophenyl)imidazole-4-carbonitrile compound had shown double Sonogashira coupling reactions with two differently substituted iodine along with the formation of two other compounds where an unusual coupling product with self-aggregation property was obtained. In other cases, monocoupling had been observed together with another compound where iodine atom present at C5 position of imidazole was replaced by hydrogen atom. 相似文献
67.
Stereoselective reductive coupling reaction of benzylic gem-dibromide promoted by Cu/polyamine produces E-stilbene derivatives with high yield under mild conditions. It provides a short pathway to synthesize symmetrical and asymmetrical E-stilbene derivatives using cheap reagents and alkenyl-free starting material together with easy workup. 相似文献
68.
Composition assessment of ferric oxide by accurate peak fitting of the Fe 2p photoemission spectrum 下载免费PDF全文
M. Bravo Sanchez J. A. Huerta‐Ruelas D. Cabrera‐German A. Herrera‐Gomez 《Surface and interface analysis : SIA》2017,49(4):253-260
A quantitative study of the surface composition of ferric oxide employing photoemission spectra is presented. It was possible to accurately reproduce the expected composition (Fe2.00±0.05O3) by modeling the background as a combination of Shirley‐type (Shirley–Vegh–Salvi–Castle) and slope backgrounds through the active approach. The line‐shape employed to fit apparent peak asymmetries was the double‐Lorentzian. It was possible to resolve a previously unreported satellite located at ~729 eV. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
69.
70.
Mechanochemical synthesis of dodecyl sulfate anion (DS−) intercalated Cu-Al layered double hydroxide
Dodecyl sulfate anion (DS−) was successfully intercalated into the gallery space of Cu-Al layered double hydroxides (LDH) by a non-heating mechanochemical route, in which basic cupric carbonate (Cu2(OH)2CO3) and aluminum hydroxide (Al(OH)3) were first dry ground and then agitated in SDS solution under ambient environment. The organics modified Cu-Al LDH showed good adsorption ability toward 2,4-dichlorophenoxyacetic acid (2, 4-D). The prepared samples were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), CHS elemental analysis and Scanning electron microscopy (SEM). The LDH precursor prepared by ball-milling could directly react with SDS molecules forming a pure phase of DS− pillared Cu-Al LDH, which was not observed with the LDH product through the ion-exchange of DS− at room temperature. The process introduced here may be applied to manufacture other types of organic modified composites for pollutants removal and other applications. 相似文献